Question on using double molds
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Tech Help, Tips, Tricks, Techniques
If it is a 3D mould, you can use it like a book mould to fill. If the filling is runny, you back off one half like its own finished piece, then turn over to adhere to the second half. If you don't need the support of the chocolate backing, make your shells but when you invert to empty, let stay inverted until it starts to set, then clean. Some will set inverted on parchment paper for cooling to insure a flat, wider edge. This will give you a thicker edge to adhere to the other half. Warm where you want the chocolate to fuse when you combine.
To do a hollow figure, as you said, put the chocolate you need in one half, seal the halves, but don't shake or you'll have nothing but bubbles. Just turn the mould in all directions so it flows everywhere. Keep turning until it sets enough to stop flowing, then cool and demould. If seasonal, you can reverse paint the inside of the mould with colored cocoa butter. Doing a hollow figure make sure the mould is no more than a few degrees cooler than your tempered chocolate, you'll need the time to get a nice even coating.